Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation
Research output: Contribution to journal › Journal article › Research › peer-review
J. Edgar Anderson, Katsuhiko Heki, Minoru Hirota, Flemming Steen Jørgensen
N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.
|Journal||Chemical communications (Cambridge, England)|
|Number of pages||2|
|Publication status||Published - 1987|