Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation

Research output: Contribution to journalJournal articleResearchpeer-review

J. Edgar Anderson, Katsuhiko Heki, Minoru Hirota, Flemming Steen Jørgensen

N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.
Original languageUndefined/Unknown
JournalChemical communications (Cambridge, England)
Volume1987
Pages (from-to)554-555
Number of pages2
ISSN1359-7345
DOIs
Publication statusPublished - 1987

ID: 38493951