Functional-Group-Tolerant Pd-Catalyzed Carbonylative Negishi Coupling with Aryl Iodides

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

Functional-Group-Tolerant Pd-Catalyzed Carbonylative Negishi Coupling with Aryl Iodides. / Kalinin, Dmitrii V.; Ulven, Trond.

In: Journal of Organic Chemistry, Vol. 88, No. 23, 2023, p. 16633-16638.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Kalinin, DV & Ulven, T 2023, 'Functional-Group-Tolerant Pd-Catalyzed Carbonylative Negishi Coupling with Aryl Iodides', Journal of Organic Chemistry, vol. 88, no. 23, pp. 16633-16638. https://doi.org/10.1021/acs.joc.3c00948

APA

Kalinin, D. V., & Ulven, T. (2023). Functional-Group-Tolerant Pd-Catalyzed Carbonylative Negishi Coupling with Aryl Iodides. Journal of Organic Chemistry, 88(23), 16633-16638. https://doi.org/10.1021/acs.joc.3c00948

Vancouver

Kalinin DV, Ulven T. Functional-Group-Tolerant Pd-Catalyzed Carbonylative Negishi Coupling with Aryl Iodides. Journal of Organic Chemistry. 2023;88(23):16633-16638. https://doi.org/10.1021/acs.joc.3c00948

Author

Kalinin, Dmitrii V. ; Ulven, Trond. / Functional-Group-Tolerant Pd-Catalyzed Carbonylative Negishi Coupling with Aryl Iodides. In: Journal of Organic Chemistry. 2023 ; Vol. 88, No. 23. pp. 16633-16638.

Bibtex

@article{b6b7ca62883e4312be870b0b825e369a,
title = "Functional-Group-Tolerant Pd-Catalyzed Carbonylative Negishi Coupling with Aryl Iodides",
abstract = "A chemoselective Pd-mediated carbonylative Negishi-type catalytic protocol for the synthesis of (hetero)aryl ketones is reported. The protocol employs the PEPPSI-IPr precatalyst and CO gas at atmospheric pressure (balloon) to foster the carbonylative coupling between diverse C(sp3)-hybridized organozinc reagents and a broad range of aryl iodides, including substrates carrying aldehyde, aniline, phenol, or carboxylic acid groups, and heteroaryls.",
author = "Kalinin, {Dmitrii V.} and Trond Ulven",
note = "Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",
year = "2023",
doi = "10.1021/acs.joc.3c00948",
language = "English",
volume = "88",
pages = "16633--16638",
journal = "Journal of Organic Chemistry",
issn = "0022-3263",
publisher = "American Chemical Society",
number = "23",

}

RIS

TY - JOUR

T1 - Functional-Group-Tolerant Pd-Catalyzed Carbonylative Negishi Coupling with Aryl Iodides

AU - Kalinin, Dmitrii V.

AU - Ulven, Trond

N1 - Publisher Copyright: © 2023 American Chemical Society.

PY - 2023

Y1 - 2023

N2 - A chemoselective Pd-mediated carbonylative Negishi-type catalytic protocol for the synthesis of (hetero)aryl ketones is reported. The protocol employs the PEPPSI-IPr precatalyst and CO gas at atmospheric pressure (balloon) to foster the carbonylative coupling between diverse C(sp3)-hybridized organozinc reagents and a broad range of aryl iodides, including substrates carrying aldehyde, aniline, phenol, or carboxylic acid groups, and heteroaryls.

AB - A chemoselective Pd-mediated carbonylative Negishi-type catalytic protocol for the synthesis of (hetero)aryl ketones is reported. The protocol employs the PEPPSI-IPr precatalyst and CO gas at atmospheric pressure (balloon) to foster the carbonylative coupling between diverse C(sp3)-hybridized organozinc reagents and a broad range of aryl iodides, including substrates carrying aldehyde, aniline, phenol, or carboxylic acid groups, and heteroaryls.

U2 - 10.1021/acs.joc.3c00948

DO - 10.1021/acs.joc.3c00948

M3 - Journal article

C2 - 37968936

AN - SCOPUS:85178573217

VL - 88

SP - 16633

EP - 16638

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 23

ER -

ID: 378764612