Structural elucidation and partial synthesis of 3-hydroxyheterodendrin, a cyanogenic glucoside from Acacia sieberiana var. woodii

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A new cyanogenic glucoside, isolated from pods of Acacia sieberiana var. woodii, was shown to be (2R)-2- (β-d-glucopyranosyloxy)-3-hydroxy-3-methylbutanenitrile by spectroscopic and chemical methods. The absolute configuration of this glucoside was correlated with that of proacacipetalin by oxymercuration of the latter, followed by borohydride reduction of the product.

Original languageEnglish
JournalPhytochemistry
Volume20
Issue number9
Pages (from-to)2221-2223
Number of pages3
ISSN0031-9422
DOIs
Publication statusPublished - 1981

    Research areas

  • 3-hydroxyheterodendrin, Acacia sieberiana var. woodii, cyanogenic glycosides, heterodendrin, Mimosoideae, Natal camelthorn, oxymercuration-demercuration., proacacipetalin

ID: 232601112