Total synthesis of ascididemin via anionic cascade ring closure
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Total synthesis of ascididemin via anionic cascade ring closure. / Petersen, Ida Nymann; Crestey, François; Kristensen, Jesper Langgaard.
In: Chemical Communications, Vol. 48, No. 72, 2012, p. 9092-9094.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Total synthesis of ascididemin via anionic cascade ring closure
AU - Petersen, Ida Nymann
AU - Crestey, François
AU - Kristensen, Jesper Langgaard
PY - 2012
Y1 - 2012
N2 - A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended to the synthesis of a new isomer of ascididemin.
AB - A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended to the synthesis of a new isomer of ascididemin.
U2 - 10.1039/c2cc34725c
DO - 10.1039/c2cc34725c
M3 - Journal article
C2 - 22864261
VL - 48
SP - 9092
EP - 9094
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 72
ER -
ID: 40379260